A Robust 3D Cage‐like Ultramicroporous Network Structure with High Gas‐Uptake Capacity

A Robust 3D Cage‐like Ultramicroporous Network Structure with High Gas‐Uptake Capacity A three‐dimensional (3D) cage‐like organic network (3D‐CON) structure synthesized by the straightforward condensation of building blocks designed with gas adsorption properties is presented. The 3D‐CON can be prepared using an easy but powerful route, which is essential for commercial scale‐up. The resulting fused aromatic 3D‐CON exhibited a high Brunauer–Emmett–Teller (BET) specific surface area of up to 2247 m2 g−1. More importantly, the 3D‐CON displayed outstanding low pressure hydrogen (H2, 2.64 wt %, 1.0 bar and 77 K), methane (CH4, 2.4 wt %, 1.0 bar and 273 K), and carbon dioxide (CO2, 26.7 wt %, 1.0 bar and 273 K) uptake with a high isosteric heat of adsorption (H2, 8.10 kJ mol−1; CH4, 18.72 kJ mol−1; CO2, 31.87 kJ mol−1). These values are among the best reported for organic networks with high thermal stability (ca. 600 °C). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Angewandte Chemie International Edition Wiley

A Robust 3D Cage‐like Ultramicroporous Network Structure with High Gas‐Uptake Capacity

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Publisher
Wiley Subscription Services, Inc., A Wiley Company
Copyright
© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
1433-7851
eISSN
1521-3773
D.O.I.
10.1002/anie.201800218
Publisher site
See Article on Publisher Site

Abstract

A three‐dimensional (3D) cage‐like organic network (3D‐CON) structure synthesized by the straightforward condensation of building blocks designed with gas adsorption properties is presented. The 3D‐CON can be prepared using an easy but powerful route, which is essential for commercial scale‐up. The resulting fused aromatic 3D‐CON exhibited a high Brunauer–Emmett–Teller (BET) specific surface area of up to 2247 m2 g−1. More importantly, the 3D‐CON displayed outstanding low pressure hydrogen (H2, 2.64 wt %, 1.0 bar and 77 K), methane (CH4, 2.4 wt %, 1.0 bar and 273 K), and carbon dioxide (CO2, 26.7 wt %, 1.0 bar and 273 K) uptake with a high isosteric heat of adsorption (H2, 8.10 kJ mol−1; CH4, 18.72 kJ mol−1; CO2, 31.87 kJ mol−1). These values are among the best reported for organic networks with high thermal stability (ca. 600 °C).

Journal

Angewandte Chemie International EditionWiley

Published: Jan 19, 2018

Keywords: ; ; ; ;

References

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