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The title molecular complex, [CoCl2(C22H18N6O)], features a novel 18‐membered Co‐containing metallocycle. The CoII atom lies in a fairly regular tetrahedral geometry defined by two imidazole N‐atom donors from one 2,5‐bis[3‐(1H‐1,3‐imidazol‐1‐ylmethyl)phenyl]‐1,3,4‐oxadiazole (L) ligand and two chloride anions. The coordinating orientation of the L ligand plays an important role in constructing the metallocycle complex. The complexes form a three‐dimensional supramolecular assembly via nonclassical C—H...Cl and C—H...N hydrogen bonds and π–π interactions.
Acta Crystallographica Section C Crystal Structure Communications – Wiley
Published: Mar 15, 2011
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