Zirconocene catalyzed synthesis of 2-substituted benzimidazole derivatives

Zirconocene catalyzed synthesis of 2-substituted benzimidazole derivatives CHO NH Cp ZrCl 2 2 NH 2 Ethanol, RT N Keywords Zirconocene dichloride  o-Phenylenediamine  Aromatic aldehydes 2-Substituted benzimidazole derivatives  Ambient temperature Introduction Organozirconocenes represent an important class of metallocenes that have garnered intensive research interest on account of their fascinating sandwich structure and unusual properties. Zirconocene dichloride is an air and moisture stable, non-hazardous, 16 electron, d organozirconocene that has been the & Vasant Helavi vbhelavi@gmail.com Department of Chemistry, Rajaram College, Kolhapur, Maharashtra 416004, India Department of Chemistry, Shivaji University, Kolhapur, Maharashtra 416004, India 123 7258 S. Karhale et al. subject of an intense research competition in the industrial sector. It is one of the most widely used metallocene-based catalysts for ethylene polymerization [1]. The catalytic activity of Cp ZrCl and other structurally related 2 2 metallocenes are attributed to their Lewis acidic character [2, 3]. Despite the interesting catalytic potential of Cp ZrCl , its applications in organic synthesis 2 2 are scarcely reported [4–6]. The catalytic phenomena occurring with Cp ZrCl 2 2 include the formation of unsaturated di-and polycyclic aluminacarbocycles [7], quinozolin-4(3H)-ones [8], 1-amidoalkyl-2-naphthols [9], 1,5-benzodiazepines [10], cyclobutenylphosphaonates [11], 5-hydroxy-1-alkenyboronates [12], intramolecular cyclization [13], pinacol coupling of aromatic aldehydes and ketones [14], http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Zirconocene catalyzed synthesis of 2-substituted benzimidazole derivatives

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Publisher
Springer Journals
Copyright
Copyright © 2016 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-016-2534-7
Publisher site
See Article on Publisher Site

Abstract

CHO NH Cp ZrCl 2 2 NH 2 Ethanol, RT N Keywords Zirconocene dichloride  o-Phenylenediamine  Aromatic aldehydes 2-Substituted benzimidazole derivatives  Ambient temperature Introduction Organozirconocenes represent an important class of metallocenes that have garnered intensive research interest on account of their fascinating sandwich structure and unusual properties. Zirconocene dichloride is an air and moisture stable, non-hazardous, 16 electron, d organozirconocene that has been the & Vasant Helavi vbhelavi@gmail.com Department of Chemistry, Rajaram College, Kolhapur, Maharashtra 416004, India Department of Chemistry, Shivaji University, Kolhapur, Maharashtra 416004, India 123 7258 S. Karhale et al. subject of an intense research competition in the industrial sector. It is one of the most widely used metallocene-based catalysts for ethylene polymerization [1]. The catalytic activity of Cp ZrCl and other structurally related 2 2 metallocenes are attributed to their Lewis acidic character [2, 3]. Despite the interesting catalytic potential of Cp ZrCl , its applications in organic synthesis 2 2 are scarcely reported [4–6]. The catalytic phenomena occurring with Cp ZrCl 2 2 include the formation of unsaturated di-and polycyclic aluminacarbocycles [7], quinozolin-4(3H)-ones [8], 1-amidoalkyl-2-naphthols [9], 1,5-benzodiazepines [10], cyclobutenylphosphaonates [11], 5-hydroxy-1-alkenyboronates [12], intramolecular cyclization [13], pinacol coupling of aromatic aldehydes and ketones [14],

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 7, 2016

References

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