Ways of controlling the selectivity of cyclohexane oxidation

Ways of controlling the selectivity of cyclohexane oxidation Operation of an industrial installation for cyclohexane oxidation was analyzed, and causes of the low process selectivity (45–52%) were elucidated. The relationships of cyclohexane oxidation under laboratory conditions maximum similar to those of the industrial process were studied. Measures were suggested for optimizing the process so as to increase the yield of the target products by a factor of 1.2–1.6, decrease the amount of cyclohexane spent for the formation of by-products by a factor of 1.2–1.8, and increase the process selectivity to 68%. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Ways of controlling the selectivity of cyclohexane oxidation

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S10704272150120101
Publisher site
See Article on Publisher Site

Abstract

Operation of an industrial installation for cyclohexane oxidation was analyzed, and causes of the low process selectivity (45–52%) were elucidated. The relationships of cyclohexane oxidation under laboratory conditions maximum similar to those of the industrial process were studied. Measures were suggested for optimizing the process so as to increase the yield of the target products by a factor of 1.2–1.6, decrease the amount of cyclohexane spent for the formation of by-products by a factor of 1.2–1.8, and increase the process selectivity to 68%.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Mar 3, 2016

References

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