Water structure and electron trapping in aqueous ionic solutions

Water structure and electron trapping in aqueous ionic solutions The optical absorption spectra observed by pulse radiolysis of alkaline (NaOH, KOH, RbOH), chloride (LiCl, MgCl2, CaCl2, NaCl, KCl) and perchloride (NaClO4) solutions at temperature 298 K are reported. Some measurements were performed at low temperature with aqueous ionic glasses. With increasing concentration of the above solutes a uniform blue-shift of the maximum of the solvated electron (e¯sol) absorption band is observed. Near infrared (NIR) spectroscopy was so used to examine the properties of water in several concentrated electrolyte solutions. It is shown that some inorganic electrolytes (e.g. NaOH, NaClO4) substantially change the water structure whereas some others (e.g. LiCl, CaCl2) influence water structure insignificantly. The correlation between the ability of excess electron trapping in electrolyte solutions and water structure deduced from NIR spectroscopy is discussed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Water structure and electron trapping in aqueous ionic solutions

Loading next page...
Brill Academic Publishers
Copyright © 2002 by VSP 2002
Chemistry; Inorganic Chemistry; Physical Chemistry; Catalysis
Publisher site
See Article on Publisher Site


You’re reading a free preview. Subscribe to read the entire article.

DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches


Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.



billed annually
Start Free Trial

14-day Free Trial