Transport properties of metacomposites in eutectic MAO4–V2O5 systems (M = Ca, Sr; A = W, Mo)

Transport properties of metacomposites in eutectic MAO4–V2O5 systems (M = Ca, Sr; A = W, Mo) Metal molybdates MMoO4 (M = Ca, Sr) and their composites with vanadium oxide V2O5 were synthesized. An X-ray diffraction analysis confirmed that the obtained molybdates were single-phase, and the heterogeneous systems were two-phase. The temperature dependences of the total conductivity of the composites were studied. The ion transport numbers in the {CaMoO4 · xV2O5} composites (x = 1–30 mol %) were studied by the EMF method. The conductivity of the composites at x ≤ 5 mol % was shown to be ionic. The conductivity of the composites was described using the mixing equation. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Electrochemistry Springer Journals

Transport properties of metacomposites in eutectic MAO4–V2O5 systems (M = Ca, Sr; A = W, Mo)

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Publisher
Springer Journals
Copyright
Copyright © 2017 by Pleiades Publishing, Ltd.
Subject
Chemistry; Electrochemistry; Physical Chemistry
ISSN
1023-1935
eISSN
1608-3342
D.O.I.
10.1134/S1023193517070060
Publisher site
See Article on Publisher Site

Abstract

Metal molybdates MMoO4 (M = Ca, Sr) and their composites with vanadium oxide V2O5 were synthesized. An X-ray diffraction analysis confirmed that the obtained molybdates were single-phase, and the heterogeneous systems were two-phase. The temperature dependences of the total conductivity of the composites were studied. The ion transport numbers in the {CaMoO4 · xV2O5} composites (x = 1–30 mol %) were studied by the EMF method. The conductivity of the composites at x ≤ 5 mol % was shown to be ionic. The conductivity of the composites was described using the mixing equation.

Journal

Russian Journal of ElectrochemistrySpringer Journals

Published: Aug 4, 2017

References

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