Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process

Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron... In this work, we developed a new method for the transformation of organostannanes via radical process. In this reaction, highly reactive carbon radical species can be efficiently generated through HBr-catalyzed photocleavage of C-Sn bond via single electron transfer process. Under aerobic conditions, the in situ formed primary/secondary alkyl radicals can be further highly selectively oxidized into carboxylic acids/ketones, respectively. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Scientific Reports Springer Journals

Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process

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Publisher
Springer Journals
Copyright
Copyright © 2017 by The Author(s)
Subject
Science, Humanities and Social Sciences, multidisciplinary; Science, Humanities and Social Sciences, multidisciplinary; Science, multidisciplinary
eISSN
2045-2322
D.O.I.
10.1038/s41598-017-16806-3
Publisher site
See Article on Publisher Site

Abstract

In this work, we developed a new method for the transformation of organostannanes via radical process. In this reaction, highly reactive carbon radical species can be efficiently generated through HBr-catalyzed photocleavage of C-Sn bond via single electron transfer process. Under aerobic conditions, the in situ formed primary/secondary alkyl radicals can be further highly selectively oxidized into carboxylic acids/ketones, respectively.

Journal

Scientific ReportsSpringer Journals

Published: Nov 29, 2017

References

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