Trans-effect in the kinetics of reactions of mixed Cu(II) acetate solvates with N-methyloctaethylporphine

Trans-effect in the kinetics of reactions of mixed Cu(II) acetate solvates with... The kinetics of complex formation reaction of N-substituted octaethylporphine (H(N-Me)(β-Et)8P] with copper(II) acetate in individual and mixed solvents based on DMSO, DMF, and Py is studied by spectrophotometry. An increase in the complex formation rate of this porphyrin with CuAc2 in mixed solvents is explained in terms of the trans-effect of the ligands in the solvate sphere of the salt. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Trans-effect in the kinetics of reactions of mixed Cu(II) acetate solvates with N-methyloctaethylporphine

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406070128
Publisher site
See Article on Publisher Site

Abstract

The kinetics of complex formation reaction of N-substituted octaethylporphine (H(N-Me)(β-Et)8P] with copper(II) acetate in individual and mixed solvents based on DMSO, DMF, and Py is studied by spectrophotometry. An increase in the complex formation rate of this porphyrin with CuAc2 in mixed solvents is explained in terms of the trans-effect of the ligands in the solvate sphere of the salt.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Jul 17, 2006

References

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