Tracing of ethyl 2-acetyl-3-(arylamino)butanoate intermediates (β-amino ketones) and their structural confinement

Tracing of ethyl 2-acetyl-3-(arylamino)butanoate intermediates (β-amino ketones) and their... Tracing of ethyl 2-acetyl-3-(phenylamino)butanoate intermediates (β-amino ketones) was performed during the course of N-arylpiperidone synthesis by reaction of aromatic amines, acetaldehyde, and ethyl acetoacetate. The structural confinement and stereochemistry of these molecules were explained by use of 2D NMR spectroscopy and X-ray crystallography. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Tracing of ethyl 2-acetyl-3-(arylamino)butanoate intermediates (β-amino ketones) and their structural confinement

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Publisher
Springer Netherlands
Copyright
Copyright © 2012 by Springer Science+Business Media B.V.
Subject
Chemistry; Inorganic Chemistry; Catalysis; Physical Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-012-0489-x
Publisher site
See Article on Publisher Site

Abstract

Tracing of ethyl 2-acetyl-3-(phenylamino)butanoate intermediates (β-amino ketones) was performed during the course of N-arylpiperidone synthesis by reaction of aromatic amines, acetaldehyde, and ethyl acetoacetate. The structural confinement and stereochemistry of these molecules were explained by use of 2D NMR spectroscopy and X-ray crystallography.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jan 26, 2012

References

  • An improved synthesis of N-aryl and N-heteroaryl substituted piperidones
    Schon, U; Messinger, J; Buckendahl, M; Prabhu, MS; Konda, A

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