To the mechanism of the isobutane alkylation with butenes

To the mechanism of the isobutane alkylation with butenes The arguments in favor of a change in the accents at the description of the reaction mechanism of the isobutene alkylation with butylenes in the presence of sulfuric acid are proposed. The reaction of sulfate sulfur reduction that until now considered as the side process is proposed to suggest as just the initiation of chain process which includes generation of tert-butyl cations. Such a concept makes it possible to explain a number of characteristic experimental data, in particular failure of attempts of creation of the effective solid catalyst for the alkylation on the basis of the sulfated zirconium oxides. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

To the mechanism of the isobutane alkylation with butenes

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2009 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S107042720904034X
Publisher site
See Article on Publisher Site

Abstract

The arguments in favor of a change in the accents at the description of the reaction mechanism of the isobutene alkylation with butylenes in the presence of sulfuric acid are proposed. The reaction of sulfate sulfur reduction that until now considered as the side process is proposed to suggest as just the initiation of chain process which includes generation of tert-butyl cations. Such a concept makes it possible to explain a number of characteristic experimental data, in particular failure of attempts of creation of the effective solid catalyst for the alkylation on the basis of the sulfated zirconium oxides.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: May 19, 2009

References

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