Thermodynamic properties of ternary systems: Calculation of standard enthalpies of solvation of triols, diols, and a series of their ethers in water-methanol mixed solvent

Thermodynamic properties of ternary systems: Calculation of standard enthalpies of solvation of... An equation for the standard enthalpy of solvation of a compound in a binary solvent is derived. The enthalpies of solvation in water-methanol mixtures are estimated for 1,3-propane-and 1,6-hexanediols, 1,2,4-butane-and 1,3,5-pentanetriols, 2-methoxy-and 2-propoxyethanols, and diethylene glycol. The enthalpy of solvation of 1,2-dimethoxyethane in the water-methanol mixed solvent is determined experimentally. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Thermodynamic properties of ternary systems: Calculation of standard enthalpies of solvation of triols, diols, and a series of their ethers in water-methanol mixed solvent

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Publisher
Springer Journals
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427206110085
Publisher site
See Article on Publisher Site

Abstract

An equation for the standard enthalpy of solvation of a compound in a binary solvent is derived. The enthalpies of solvation in water-methanol mixtures are estimated for 1,3-propane-and 1,6-hexanediols, 1,2,4-butane-and 1,3,5-pentanetriols, 2-methoxy-and 2-propoxyethanols, and diethylene glycol. The enthalpy of solvation of 1,2-dimethoxyethane in the water-methanol mixed solvent is determined experimentally.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Dec 28, 2006

References

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