A mathematical model of a multistage process of thermocatalytic decomposition of 1-methyl-cyclohexyl hydroperoxide in the presence of sodium stearate is developed. A procedure for calculating the unknown rate and equilibrium constants of the elementary and overall reaction stages is described. It is based on an analysis of the kinetic relationships in consumption of the initial products and accumulation of the intermediate and final products of thermocatalytic decomposition, with account of the known constants for individual stages.
Russian Journal of Applied Chemistry – Springer Journals
Published: Mar 22, 2005
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