Thermal decomposition study of chloride-containing complex ammonium nitrate-based fertilizers by thermogravimetry and differential scanning calorimetry

Thermal decomposition study of chloride-containing complex ammonium nitrate-based fertilizers by... Thermogravimetry and differential scanning calorimetry were used to study the thermal properties of chloride-containing complex ammonium nitrate-based fertilizers produced with various degrees of phosphoric acid ammonization on the basis of ammonium nitrate. Isoconversion integral methods were used to calculate the dependence of the activation energy on the degree of exothermic decomposition. It was shown that the exothermic decomposition process occurs in several stages. A conclusion was made on the basis of the results obtained that the thermal decomposition of these types of fertilizers is affected by the degree of ammonization and by the component ratio. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Thermal decomposition study of chloride-containing complex ammonium nitrate-based fertilizers by thermogravimetry and differential scanning calorimetry

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Publisher
Pleiades Publishing
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216090019
Publisher site
See Article on Publisher Site

Abstract

Thermogravimetry and differential scanning calorimetry were used to study the thermal properties of chloride-containing complex ammonium nitrate-based fertilizers produced with various degrees of phosphoric acid ammonization on the basis of ammonium nitrate. Isoconversion integral methods were used to calculate the dependence of the activation energy on the degree of exothermic decomposition. It was shown that the exothermic decomposition process occurs in several stages. A conclusion was made on the basis of the results obtained that the thermal decomposition of these types of fertilizers is affected by the degree of ammonization and by the component ratio.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jan 3, 2017

References

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