The synergistic inhibition effect between imidazoline-based dissymmetric bis-quaternary ammonium salts and thiourea on Q235 steel in CO2 corrosion process

The synergistic inhibition effect between imidazoline-based dissymmetric bis-quaternary ammonium... The inhibition effect of imidazoline-based dissymmetric bis-quaternary ammonium salt (DBA) and Thiourea (TU) on Q235 steel in CO2-saturated simulated oilfield-produced water was studied by means of the weight-loss method, polarization and electrochemical impedance spectroscopy (EIS). The polarization measurements reveal that the compound inhibitors are anodic-type inhibitors that mainly inhibit the anodic process. EIS results show that the changes in the impedance parameters are due to the formation of a protective layer on the Q235 steel surface by the adsorption of inhibitor molecules. The results of energy dispersive X-ray spectroscopy and scanning electron microscopy confirm the existence of the protective layer. The results also show that adsorption model obeys to the Flory–Huggins adsorption isotherm. The synergism parameter suggests that the synergistic effect is obvious at concentrations of 100 and 200 mg L−1, and there is a cooperative mechanism between the DBA and TU. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

The synergistic inhibition effect between imidazoline-based dissymmetric bis-quaternary ammonium salts and thiourea on Q235 steel in CO2 corrosion process

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Publisher
Springer Netherlands
Copyright
Copyright © 2015 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-015-2047-9
Publisher site
See Article on Publisher Site

Abstract

The inhibition effect of imidazoline-based dissymmetric bis-quaternary ammonium salt (DBA) and Thiourea (TU) on Q235 steel in CO2-saturated simulated oilfield-produced water was studied by means of the weight-loss method, polarization and electrochemical impedance spectroscopy (EIS). The polarization measurements reveal that the compound inhibitors are anodic-type inhibitors that mainly inhibit the anodic process. EIS results show that the changes in the impedance parameters are due to the formation of a protective layer on the Q235 steel surface by the adsorption of inhibitor molecules. The results of energy dispersive X-ray spectroscopy and scanning electron microscopy confirm the existence of the protective layer. The results also show that adsorption model obeys to the Flory–Huggins adsorption isotherm. The synergism parameter suggests that the synergistic effect is obvious at concentrations of 100 and 200 mg L−1, and there is a cooperative mechanism between the DBA and TU.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 18, 2015

References

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