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- Publisher
- Springer Journals
- Copyright
- Copyright © 2015 by Pleiades Publishing, Ltd.
- Subject
- Chemistry; Physical Chemistry; Inorganic Chemistry
- ISSN
- 1070-3284
- eISSN
- 1608-3318
- DOI
- 10.1134/S1070328415040090
- Publisher site
- See Article on Publisher Site
Abstract
A new tetranuclear cubane-like copper(II) complex [Cu4(HL1)4] based on N-(1,1-dihydroxymethyl)ethyl-βalanine (H3L1) is synthesized. Its structure is studied by X-ray diffraction analysis (CIF file CCDC 1020735). In the crystal structure of the complex, the copper atoms are joined into tetrahedra with the distances Cu⋯Cu 3.139–3.456 Å supplemented to cubanes by the μ3-bridging oxygen atoms of the hydroxymethyl groups. The coordination environment of each metal center is a distorted octahedron. The (HL1)2− ligand is doubly protonated and performs the hexadentate chelate-(μ3-bridging) function to form the alkoxocarboxylate chelate of copper(II).
Journal
Russian Journal of Coordination Chemistry – Springer Journals
Published: Apr 9, 2015