The reactions and composition of the surface intermediate species in the selective catalytic reduction of NO x with ethylene over Co-ZSM-5

The reactions and composition of the surface intermediate species in the selective catalytic... A pretreatment-transient reaction product analysis method was applied to study the reactions and average composition of the possible surface intermediate species in selective catalytic reduction with ethylene of NO x over Co-ZSM-5. The reactions of the surface species, formed by the pretreatment of Co-ZSM-5 in a NO/C2H4/O2 mixture at 275°C, with the NO/O2 flow produced much more N2 than that with the individual NO or O2 flow. The similarity of N2/CO x /H2O product distribution generated from the above surface species-NO/O2 reactions and that from the normal NO/C2H4/O2 flow reactions implies that the surface species NC a O b H c formed in the three-component pretreatment process is very likely the primary intermediate surface species generated during the real flow reactions. The in situ FT-IR (DRIFT) spectroscopy measurements of the surface species support the above conclusion. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

The reactions and composition of the surface intermediate species in the selective catalytic reduction of NO x with ethylene over Co-ZSM-5

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Publisher
Brill Academic Publishers
Copyright
Copyright © 2007 by VSP
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856707782565877
Publisher site
See Article on Publisher Site

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