The regular features of the reaction of calcium, barium, and zinc chlorides with oxygen to form molecular chlorine and corresponding metal oxides are studied. The rate constants of the reaction were determined. The effective activation energies of oxidation of chloride ions were calculated with due to regard for the diffusion at the gas-chloride melt interface, which is especially pronounced at a temperature above 550°C. Zinc oxide being formed was separated from the reaction mixture, and the dispersion of its particles was determined.
Russian Journal of Applied Chemistry – Springer Journals
Published: Sep 24, 2010
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