The intercalation of metalloporphyrin complex anions into layered double hydroxides

The intercalation of metalloporphyrin complex anions into layered double hydroxides Investigations to elucidate the structures of the cobalt(III) and manganese(III) complexes of tetra(p-sulfonatophenyl)porphinate anions (M(III)TSPP; M = Co and Mn), intercalated in Mg-Fe/Cl and Mg-Al/Cl layered double hydroxides (LDHs) have been carried out. Powder X-ray diffraction analysis, IR and UV-vis diffuse reflectance spectroscopy of Co(III)TSPP and Mn(III)TSPP intercalated into the interlayer spaces of LDH resulted in their perpendicular alignment against the host layers in the plane of the hybrid. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

The intercalation of metalloporphyrin complex anions into layered double hydroxides

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Publisher
Brill Academic Publishers
Copyright
Copyright © 2003 by VSP 2003
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856703764929994
Publisher site
See Article on Publisher Site

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