The Effect of Sesquioxides of 3d-Transition Elements on the Strength of Synthetic Mullite and Mullite-Based Materials

The Effect of Sesquioxides of 3d-Transition Elements on the Strength of Synthetic Mullite and... Mullite synthesized from alumina and silica with the sesquioxide of a 3d-transition metal added (Me = Sc, Ti, V, Cr, Mn, and Fe) is capable of forming solid solutions of composition Al6–x Me xSi2O13. It is shown, using data obtained by methods of x-ray phase analysis, electron paramagnetic resonance, infrared spectroscopy and magnetic susceptibility, that the aluminum atoms located at octahedral positions of the mullite lattice can be isomorphously replaced by Me metals. The effect of this replacement on the strength of mullite and mullite-based ceramics is considered. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Refractories and Industrial Ceramics Springer Journals

The Effect of Sesquioxides of 3d-Transition Elements on the Strength of Synthetic Mullite and Mullite-Based Materials

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Publisher
Kluwer Academic Publishers-Plenum Publishers
Copyright
Copyright © 2001 by Plenum Publishing Corporation
Subject
Materials Science; Characterization and Evaluation of Materials; Materials Science, general; Ceramics, Glass, Composites, Natural Materials
ISSN
1083-4877
eISSN
1573-9139
D.O.I.
10.1023/A:1014070613886
Publisher site
See Article on Publisher Site

Abstract

Mullite synthesized from alumina and silica with the sesquioxide of a 3d-transition metal added (Me = Sc, Ti, V, Cr, Mn, and Fe) is capable of forming solid solutions of composition Al6–x Me xSi2O13. It is shown, using data obtained by methods of x-ray phase analysis, electron paramagnetic resonance, infrared spectroscopy and magnetic susceptibility, that the aluminum atoms located at octahedral positions of the mullite lattice can be isomorphously replaced by Me metals. The effect of this replacement on the strength of mullite and mullite-based ceramics is considered.

Journal

Refractories and Industrial CeramicsSpringer Journals

Published: Oct 9, 2004

References

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