Changes in phase composition and properties of cordierite-based materials depending on the calcination temperature and the calcined talcum/raw talcum ratio in the starting mixture is studied. Periodic features in the behavior of the MgO – Al2O3 – SiO2 system are analyzed in terms of a conjugation scheme of solid-phase reversible chemical reactions. Routes for the spinodal phase decompositions of sapphirine and cordierite solid solutions are proposed. Conditions for formation of a dissipative structure in refractory materials and a specific organization of the phase composition under spinodal decomposition of solid solutions are considered.
Refractories and Industrial Ceramics – Springer Journals
Published: Oct 9, 2004
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