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References (36)
-
Y. Ilan, J. Rabani, A. Henglein (1976)
Pulse radiolytic investigations of peroxy radicals produced from 2-propanol and methanol. [12 MeV electron pulses of 100-ns duration]The Journal of Physical Chemistry, 80
-
M. Simic, P. Neta, E. Hayon (1969)
Pulse radiolysis study of alcohols in aqueous solutionThe Journal of Physical Chemistry, 73
-
M. Wong, A. Pross, L. Radom (1994)
COMPARISON OF THE ADDITION OF CH3., CH2OH., AND CH2CN. RADICALS TO SUBSTITUTED ALKENES : A THEORETICAL STUDY OF THE REACTION MECHANISMJournal of the American Chemical Society, 116
-
Torsten Zytowski, H. Fischer (1996)
Absolute Rate Constants for the Addition of Methyl Radicals to Alkenes in Solution: New Evidence for Polar InteractionsJournal of the American Chemical Society, 118
-
J. Rabani, D. Klug-Roth, A. Henglein (1974)
Pulse radiolytic investigations of OHCH2O2 radicalsThe Journal of Physical Chemistry, 78
-
S. Steenken, P. Neta (1982)
Oxidation of substituted alkyl radicals by hexachloroiridate(2-), hexacyanoferrate(3-), and permanganate ions in aqueous solution. Electron transfer versus chlorine transfer from hexachloroiridate(2-) ionChemInform, 13
-
M. D'Angelantonio, S. Emmi, G. Poggi, G. Beggiato (1999)
Reaction of the OH Radical with Furfural. Spectral and Kinetic Investigation by Pulse Radiolysis and by ab Initio and Semiempirical MethodsJournal of Physical Chemistry A, 103
-
X. Shen, J. Lind, T. Eriksen, G. Merényi (1989)
Reactivity of the trichloromethylperoxo radical: evidence for a first-order transformationThe Journal of Physical Chemistry, 93
-
G. Dey, D. Naik, K. Kishore, P. Moorthy (1994)
Kinetic and spectral characteristics of transients formed in the pulse radiolysis of phenylthiourea in aqueous solutionRadiation Physics and Chemistry, 43
-
C. Jonah, J. Spinks, R. Woods (1964)
Introduction to Radiation Chemistry -
J. Mönig, D. Bahnemann, K. Asmus (1983)
One electron reduction of CCl4 in oxygenated aqueous solutions: a CCl3O2-free radical mediated formation of Cl- and CO2.Chemico-biological interactions, 47 1
-
G. Czapski, J. Holcman, B. Bielski (1994)
Reactivity of nitric oxide with simple short-lived radicals in aqueous solutionsJournal of the American Chemical Society, 116
-
J. Grodkowski, P. Neta, C. Schlesener, J. Kochi (1985)
Rates and mechanisms of reduction of tris(phenanthroline)iron(III) by various radicals: effect of solventThe Journal of Physical Chemistry, 89
-
J. Rabani, W. Mulac, M. Matheson (1977)
Pulse radiolysis studies of zinc(1+) ion reactionsThe Journal of Physical Chemistry, 81
-
Y. Lee, S. Schwartz (1981)
Reaction kinetics of nitrogen dioxide with liquid water at low partial pressureThe Journal of Physical Chemistry, 85
-
B. Maillard, K. Ingold, J. Scaiano (1983)
Rate constants for the reactions of free radicals with oxygen in solutionJournal of the American Chemical Society, 105
-
Alexandra Sauer, H. Cohen, D. Meyerstein (1988)
The methyl(cyclam)nickel(III) dication in aqueous solutions: determination of the equilibrium constant of homolysis, kinetics of oxygen insertion, and methyl transfer to aquated chromium(2+)Inorganic Chemistry, 27
-
B. Bielski, D. Cabelli, R. Arudi, A. Ross (1985)
Reactivity of HO2/O−2 Radicals in Aqueous SolutionJournal of Physical and Chemical Reference Data, 14
-
Glyn Phillips (1961)
Radiation chemistry of carbohydrates.Advances in carbohydrate chemistry, 16
-
K. Schmidt, P. Han, D. Bartels (1995)
Radiolytic Yields of the Hydrated Electron from Transient Conductivity. Improved Calculation of the Hydrated Electron Diffusion Coefficient and Analysis of Some Diffusion-Limited (e-)aq Reaction RatesThe Journal of Physical Chemistry, 99
-
R. Huie, L. Shoute, P. Neta (1991)
Temperature dependence of the rate constants for reactions of the carbonate radical with organic and inorganic reductantsInternational Journal of Chemical Kinetics, 23
-
S. Steenken, C. Warren, B. Gilbert (1990)
Generation of radical-cations from naphthalene and some derivatives, both by photoionization and reaction with SO4–˙: formation and reactions studied by laser flash photolysisJournal of The Chemical Society-perkin Transactions 1
-
G. Buxton, C. Greenstock, W. Helman, A. Ross (1988)
Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in Aqueous SolutionJournal of Physical and Chemical Reference Data, 17
-
Q. Mulazzani, M. D'Angelantonio, M. Venturi, M. Hoffman, M. Rodgers (1986)
Interaction of formate and oxalate ions with radiation-generated radicals in aqueous solution. Methylviologen as a mechanistic probeThe Journal of Physical Chemistry, 90
-
P. Neta, R. Huie, A. Ross (1979)
Rate Constants for Reactions of Inorganic Radicals in Aqueous SolutionJournal of Physical and Chemical Reference Data, 17
-
S. Jovanovic, I. Janković, Ljubica Josimović (1992)
Electron-transfer reactions of alkylperoxy radicalsJournal of the American Chemical Society, 114
-
A. Heberger, B. Lopata (1998)
Assessment of Nucleophilicity and Electrophilicity of Radicals, and of Polar and Enthalpy Effects on Radical Addition Reactions1Journal of Organic Chemistry, 63
-
G. Nahor (1988)
Formation and decay of zinc tetrakis(N-methyl-4-pyridinio) porphyrin .pi.-radical cation in aqueous solutions containing azide ions and a polyelectrolyteThe Journal of Physical Chemistry, 92
-
H. Schwarz, R. Dodson (1989)
Reduction potentials of CO2- and the alcohol radicalsThe Journal of Physical Chemistry, 93
-
P. O'Neill, S. Steenken, D. Schulte‐Frohlinde (1975)
Formation of radical cations of methoxylated benzenes by reaction with hydroxyl radicals, thallium(2+), silver(2+), and peroxysulfate (SO4.-) in aqueous solution. Optical and conductometric pulse radiolysis and in situ radiolysis electron spin resonance studyThe Journal of Physical Chemistry, 79
-
B. Hickel (1975)
Absorption spectra and kinetics of methyl and ethyl radicals in waterThe Journal of Physical Chemistry, 79
-
S. Emmi, M. D'Angelantonio, G. Poggi, M. Russo, A. Beggiato, B. Larsen (2002)
The selective OH radical oxidation of sorbitylfurfural: A combined experimental and theoretical studyJournal of Physical Chemistry A, 106
-
K. Henbest, P. Douglas, M. Garley, A. Mills (1994)
Persulphate quenching of the excited state of ruthenium(II) tris-bipyridyl dication: thermal reactionsJournal of Photochemistry and Photobiology A-chemistry, 80
-
P. Jiang, Y. Katsumura, R. Nagaishi, Masahumi Domae, K. Ishikawa, K. Ishigure, Y. Yoshida (1992)
Pulse radiolysis study of concentrated sulfuric acid solutions. Formation mechanism, yield and reactivity of sulfate radicalsJournal of the Chemical Society, Faraday Transactions, 88
-
J. Wright, E. Johnson, G. DiLabio (2001)
Predicting the activity of phenolic antioxidants: theoretical method, analysis of substituent effects, and application to major families of antioxidants.Journal of the American Chemical Society, 123 6
-
P. Neta, V. Madhavan, H. Zemel, R. Fessenden (2002)
Rate constants and mechanism of reaction of sulfate radical anion with aromatic compoundsChemInform, 8
- Publisher
- Springer Journals
- Copyright
- 2004 VSP
- Subject
- Chemistry; Inorganic Chemistry; Physical Chemistry; Catalysis
- ISSN
- 0922-6168
- eISSN
- 1568-5675
- DOI
- 10.1163/156856704323033996
- Publisher site
- See Article on Publisher Site
Abstract
Ionising radiations, employed in a broad range of dose-rate, together with a complex non-linear computation of reaction mechanisms, allow the determination of boundary values of rate constants concerning sorbitylfurfural (SF) reactivity towards a wide series of oxidant and/or virtually harmful radicals. SF reacts with some radicals (H, SO4-˙, CO3-˙, Br2-˙, CH3˙), produced with both pulse and stationary radiolysis in neutral aqueous solution, having electrophilic and/or oxidative behaviour. The rate constants range from diffusional (k = (7-9) × 109 M-1 s-1) to relatively low values (k = 2 × 105 M-1 s-1). The possibility to observe these reactions, by means of radiolytical techniques, is heavily influenced by dose-rate. A relation between the radical E0NHE and their reactivity with SF is hinted.
Journal
Research on Chemical Intermediates – Springer Journals
Published: Apr 1, 2004