Synthetic Anionophores for Basic Anions as “Presumably, OH−/Cl− Antiporters”: From the Synthetic Ion Channels to Multi-ion Hopping, Anti-Hofmeister Selectivity, and Strong Positive AMFE

Synthetic Anionophores for Basic Anions as “Presumably, OH−/Cl− Antiporters”: From the... J Membrane Biol (2014) 247:651–665 DOI 10.1007/s00232-014-9683-7 O R I G IN AL ARTI CL ES Synthetic Anionophores for Basic Anions as ‘‘Presumably, 2 2 OH /Cl Antiporters’’: From the Synthetic Ion Channels to Multi-ion Hopping, Anti-Hofmeister Selectivity, and Strong Positive AMFE Sofya Kostina Berezin Received: 18 December 2013 / Accepted: 13 May 2014 / Published online: 11 June 2014 Springer Science+Business Media New York 2014 Abstract We describe application of theory and kinetic implications of findings to the particular field and beyond modeling to study transport of basic anions by the small are discussed. synthetic molecules. The findings should equip researchers in the particular field with a tool necessary to address an Keywords Proton and hydroxide permeability  Anion essential question: whether a given anion transporter exchange  Anionophore  Anomalous Mole-Fraction - - - - facilitates permeation of F ,CH COO ,N , and SCN Effect (AMFE)  Synthetic ion channels  Basic anions 3 3 across biological membrane or it does not. The basic anions undergo hydrolysis and conjugate acids (HAnion) are permeant species. However, because methods to Introduction quantitatively account for HAnion transport do not exist, traditionally, the phenomenon is also treated as non-exist- Number http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png The Journal of Membrane Biology Springer Journals

Synthetic Anionophores for Basic Anions as “Presumably, OH−/Cl− Antiporters”: From the Synthetic Ion Channels to Multi-ion Hopping, Anti-Hofmeister Selectivity, and Strong Positive AMFE

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Publisher
Springer US
Copyright
Copyright © 2014 by Springer Science+Business Media New York
Subject
Life Sciences; Biochemistry, general; Human Physiology
ISSN
0022-2631
eISSN
1432-1424
D.O.I.
10.1007/s00232-014-9683-7
Publisher site
See Article on Publisher Site

Abstract

J Membrane Biol (2014) 247:651–665 DOI 10.1007/s00232-014-9683-7 O R I G IN AL ARTI CL ES Synthetic Anionophores for Basic Anions as ‘‘Presumably, 2 2 OH /Cl Antiporters’’: From the Synthetic Ion Channels to Multi-ion Hopping, Anti-Hofmeister Selectivity, and Strong Positive AMFE Sofya Kostina Berezin Received: 18 December 2013 / Accepted: 13 May 2014 / Published online: 11 June 2014 Springer Science+Business Media New York 2014 Abstract We describe application of theory and kinetic implications of findings to the particular field and beyond modeling to study transport of basic anions by the small are discussed. synthetic molecules. The findings should equip researchers in the particular field with a tool necessary to address an Keywords Proton and hydroxide permeability  Anion essential question: whether a given anion transporter exchange  Anionophore  Anomalous Mole-Fraction - - - - facilitates permeation of F ,CH COO ,N , and SCN Effect (AMFE)  Synthetic ion channels  Basic anions 3 3 across biological membrane or it does not. The basic anions undergo hydrolysis and conjugate acids (HAnion) are permeant species. However, because methods to Introduction quantitatively account for HAnion transport do not exist, traditionally, the phenomenon is also treated as non-exist- Number

Journal

The Journal of Membrane BiologySpringer Journals

Published: Jun 11, 2014

References

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