A new coordination polymer Mn2(L)(DMF)2(H2O)2 (I), H4L = 2,3′,5,5′-biphenyl tetracarboxylic acid has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The X-ray diffraction analysis shows that I (C22H20Mn2N2O12) crystallizes in the monoclinic crystal system space group P21. The magnetic studies of I showed that there exist antiferromagnetic interactions between the Mn(II) centres. The unit cell parameters for I: a = 9.6271(13), b = 13.1172(17), c = 10.5726(14) Å, β = 110.084(2)°, V = 1253.9(3)Å3, Z = 2.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Jun 24, 2015
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