Synthesis, strucure, and magnetic property of a 3D Mn(II) coordination polymer based on 2,3′,5,5′-bophenyl tetracarboxylic acid

Synthesis, strucure, and magnetic property of a 3D Mn(II) coordination polymer based on... A new coordination polymer Mn2(L)(DMF)2(H2O)2 (I), H4L = 2,3′,5,5′-biphenyl tetracarboxylic acid has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The X-ray diffraction analysis shows that I (C22H20Mn2N2O12) crystallizes in the monoclinic crystal system space group P21. The magnetic studies of I showed that there exist antiferromagnetic interactions between the Mn(II) centres. The unit cell parameters for I: a = 9.6271(13), b = 13.1172(17), c = 10.5726(14) Å, β = 110.084(2)°, V = 1253.9(3)Å3, Z = 2. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis, strucure, and magnetic property of a 3D Mn(II) coordination polymer based on 2,3′,5,5′-bophenyl tetracarboxylic acid

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415070106
Publisher site
See Article on Publisher Site

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