Synthesis, structure, and catalytic oxidation of a molybdenum(VI) complex [MoO2(CH3OH)L]

Synthesis, structure, and catalytic oxidation of a molybdenum(VI) complex [MoO2(CH3OH)L] A new molybdenum(VI) complex, [MoO2(CH3OH)(L)] (L = N′-(4-diethylamino-2-hydroxybenzylidene)-4-hydroxybenzohydrazide), was prepared and characterized by spectroscopy methods and single crystal X-ray diffraction (CIF file CCDC no. 1038153). The crystal of the complex, C19H23MoN3O6, crystallizes in the triclinic space group $$P\bar 1$$ with unit cell dimensions a = 6.9824(9), b = 10.206(1), c = 15.302(2) Å, α = 94.399(2)°, β = 101.877(2)°, γ = 104.062(2)°, V = 1025.9(2) Å3, Z = 2, R 1 = 0.0317, wR 2 = 0.0796, S = 1.060. The Mo atom in the complex is in an octahedral coordination with phenolate O, imino N, enolate O atoms of the ligand L, and one oxo O in the equatorial plane, and with one methanol O and the other oxo O in the axial sites. Crystals of the complex are stabilized by hydrogen bonds. The complex was studied for its catalytic oxidation property on some olefins, with tert-butyl hydrogen peroxide as oxidant. Russian Journal of Coordination Chemistry Springer Journals

Synthesis, structure, and catalytic oxidation of a molybdenum(VI) complex [MoO2(CH3OH)L]

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Pleiades Publishing
Copyright © 2015 by Pleiades Publishing, Ltd.
Chemistry; Physical Chemistry; Inorganic Chemistry
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