Synthesis, structural characterization, and properties of a Cd(II) complex with a carboxylate- and benzimidazolyl-containing ligand

Synthesis, structural characterization, and properties of a Cd(II) complex with a carboxylate-... The hydrothermal reaction of cadmium salt with 3,5-bis(benzimidazol-1-ylmethyl)benzoic acid (HL) forms a new complex [Cd(L)2] · 3H2O (I). This complex has been characterized by single-crystal X-ray diffraction, IR, elemental and thermogravimetric analyses and shows 3D flu framework structure with 2-nodal (3,6)-connected (42.6)2(44.62.89) topology. Luminescent property of I was investigated. Moreover, single crystals of HL were obtained accidentally in the hydrothermal reaction of the HL with MnSO4 at 160°C, and its crystal structure has been characterized by single-crystal X-ray diffraction (CIF files CCDC nos. 1020274 (HL) and 1020275 (I)). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis, structural characterization, and properties of a Cd(II) complex with a carboxylate- and benzimidazolyl-containing ligand

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415060020
Publisher site
See Article on Publisher Site

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