Synthesis, structural, and luminescence of two coordination polymers

Synthesis, structural, and luminescence of two coordination polymers A organic compound and its lanthanide coordination polymer with chemical formulae HL1, {[La(L1)3(H2O)2] · 2H2O · 2,2'-Bipy} (I), (HL1 = 3-(4-hydroxyphenyl)propanoic acid, 2,2'-Bipy = 2,2'-bipyridine) have been synthesized and structurally characterized. Organic compound HL1 shows 1D supramolecular chain constructing from intermolecular hydrogen-bonded interaction. Complex II has 1D infinite chain with a [La(L1)3] n dimeric repeat unit with lanthanide in a nine-coordinate environment. Furthermore, the luminescent properties of the two compounds were discussed in detail (CIF files CCDC nos. 1045032 (HL1), 1045033 (I)). Russian Journal of Coordination Chemistry Springer Journals

Synthesis, structural, and luminescence of two coordination polymers

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Pleiades Publishing
Copyright © 2015 by Pleiades Publishing, Ltd.
Chemistry; Physical Chemistry; Inorganic Chemistry
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