Synthesis, structural, and luminescence of two coordination polymers

Synthesis, structural, and luminescence of two coordination polymers A organic compound and its lanthanide coordination polymer with chemical formulae HL1, {[La(L1)3(H2O)2] · 2H2O · 2,2'-Bipy} (I), (HL1 = 3-(4-hydroxyphenyl)propanoic acid, 2,2'-Bipy = 2,2'-bipyridine) have been synthesized and structurally characterized. Organic compound HL1 shows 1D supramolecular chain constructing from intermolecular hydrogen-bonded interaction. Complex II has 1D infinite chain with a [La(L1)3] n dimeric repeat unit with lanthanide in a nine-coordinate environment. Furthermore, the luminescent properties of the two compounds were discussed in detail (CIF files CCDC nos. 1045032 (HL1), 1045033 (I)). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis, structural, and luminescence of two coordination polymers

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415080035
Publisher site
See Article on Publisher Site

Abstract

A organic compound and its lanthanide coordination polymer with chemical formulae HL1, {[La(L1)3(H2O)2] · 2H2O · 2,2'-Bipy} (I), (HL1 = 3-(4-hydroxyphenyl)propanoic acid, 2,2'-Bipy = 2,2'-bipyridine) have been synthesized and structurally characterized. Organic compound HL1 shows 1D supramolecular chain constructing from intermolecular hydrogen-bonded interaction. Complex II has 1D infinite chain with a [La(L1)3] n dimeric repeat unit with lanthanide in a nine-coordinate environment. Furthermore, the luminescent properties of the two compounds were discussed in detail (CIF files CCDC nos. 1045032 (HL1), 1045033 (I)).

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Sep 2, 2015

References

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