Synthesis, spectral, thermal, and a crystalline structure of complexes containing [MeC(CH2PPh2)3Cu(I)]

Synthesis, spectral, thermal, and a crystalline structure of complexes containing... The preparation of new [MeC(CH2PPh2)3CuCl] 1 and its derivatives was carried out directly by mixing of CuCl and MeC(CH2PPh2)3 ligand in dry THF, the neutral precursor 1 served to prepare [MeC(CH2PPh2)3Cu(NCCH3)]BF4 2 and [MeC(CH2PPh2)3Cu(PCH2Ph)3]BF4 3. These complexes are characterized on the basis of elemental analysis, IR, EDS, 1H, 13C and 31P{1H}NMR, FAB-MS, TG/DTA and single-crystal X-ray diffraction studies. Complex 1 crystallizes in the Orthorhombic unit cells with the space group Pna2(1). The structural behavior of MeC(CH2PPh2)3 ligand in the formed complexes during the coordination reaction was monitored by 31P{1H}NMR in CDCl3 at room temperature for the first time. Research on Chemical Intermediates Springer Journals

Synthesis, spectral, thermal, and a crystalline structure of complexes containing [MeC(CH2PPh2)3Cu(I)]

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Springer Netherlands
Copyright © 2012 by Springer Science+Business Media B.V.
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
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