Synthesis of TiO2 hollow spheres using binary ionic liquids as an electrocatalyst

Synthesis of TiO2 hollow spheres using binary ionic liquids as an electrocatalyst Titanium dioxide (TiO2 titania) hollow sphere was simply synthesized using various ionic liquids (ILs). The shape and size of TiO2 particles were significantly different with the composition of ILs. This is mainly attributed to the interaction between organic solvent and IL at the interface leading to the formation of sphere. Among the binary ILs, [Bmim][BF4] + [Omim][PF6], [Bmim][BF4] + [Omim][PF6], and [Bmim][PF6] + [Hmim][PF6] were useful to prepare TiO2 nanostructures with high surface area and anatase phase. Especially, [Bmim][BF4] + [Omim][PF6] was the most effective IL to synthesize an anatase TiO2 hollow sphere. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Synthesis of TiO2 hollow spheres using binary ionic liquids as an electrocatalyst

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Publisher
Springer Journals
Copyright
Copyright © 2011 by Springer Science+Business Media B.V.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry; Catalysis
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-011-0400-1
Publisher site
See Article on Publisher Site

Abstract

Titanium dioxide (TiO2 titania) hollow sphere was simply synthesized using various ionic liquids (ILs). The shape and size of TiO2 particles were significantly different with the composition of ILs. This is mainly attributed to the interaction between organic solvent and IL at the interface leading to the formation of sphere. Among the binary ILs, [Bmim][BF4] + [Omim][PF6], [Bmim][BF4] + [Omim][PF6], and [Bmim][PF6] + [Hmim][PF6] were useful to prepare TiO2 nanostructures with high surface area and anatase phase. Especially, [Bmim][BF4] + [Omim][PF6] was the most effective IL to synthesize an anatase TiO2 hollow sphere.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Sep 9, 2011

References

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