Reaction of 1-amidino-3-arylthioureas (1) with aryl isothiocyanates yielded 1-aryl-2-arylamino-4-imino-1,4,5,6-tetrahydro-1,3,5-triazine-6-thiones (3) which contained the more electron releasing aryl substituent at the ring nitrogen. The reaction of the S-benzyl derivatives of (1) with aryl isothiocyanates could be directed to give the same type of triazinethione derivatives but with the desired aryl substituent at the ring nitrogen.
Research on Chemical Intermediates – Springer Journals
Published: Apr 14, 2009
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