Synthesis of SKOP oligopiperylene rubber on vanadium catalytic systems

Synthesis of SKOP oligopiperylene rubber on vanadium catalytic systems Specific features of cationic polymerization of 1,3-pentadiene under the action of modified catalytic systems based on vanadium oxytrichloride were studied. The most effective agents controlling the molecular characteristics in synthesis of poly-1,3-pentadiene on vanadium catalysts are tert-butyl chloride and a combination of tert-butyl chloride with diisopropyl ether. The suggested catalytic systems allow virtually complete conversion of the monomer to be reached within a technologically acceptable time. The developed vanadium catalytic systems are recommended for commercial production of Oligopiperylene Rubber SKOP. Russian Journal of Applied Chemistry Springer Journals

Synthesis of SKOP oligopiperylene rubber on vanadium catalytic systems

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Pleiades Publishing
Copyright © 2015 by Pleiades Publishing, Ltd.
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
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