Synthesis of phenyl azides bearing (E)-2-halovinyl group

Synthesis of phenyl azides bearing (E)-2-halovinyl group A series of phenyl azides bearing (E)-2-halovinyl groups were synthesized in high yields by treatment of (E)-3-(4-azidophenyl)- and (E)-3-(2-azidophenyl)acrylic acid with N-halosuccinimide in the presence of LiOAc. (E)-4-(2-bromovinyl) phenyl azide, one of the synthesized intermediates, was selected to transform to a diverse range of phenyl-1, 2, 3-triazoles bearing (E)-4-(2-bromovinyl) groups by Cu(I)-catalyzed 1,3-dipolar cycloaddition reaction. Research on Chemical Intermediates Springer Journals

Synthesis of phenyl azides bearing (E)-2-halovinyl group

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Springer Netherlands
Copyright © 2011 by Springer Science+Business Media B.V.
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
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