Precursor compounds [Co(NH3)6][Rh(NO2)6] and [Co(NH3)6][Co(NO2)6], solid solutions [Co(NH3)6] [Rh(NO2)6]1−x [Co(NO2)6] x , and solid solutions Na3[Rh1−x Co x (NO2)6] were synthesized and studied by IR spectroscopy and elemental, X-ray phase, X-ray diffraction, and thermogravimetric analyses. X-ray phase analysis was employed to examine products of thermal decomposition of precursors in the atmospheres of hydrogen and helium. Catalysts with a Co-Rh active system, supported by ZrO2, were prepared and tested in the reaction of steam conversion of ethanol.
Russian Journal of Applied Chemistry – Springer Journals
Published: Nov 20, 2011
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