Synthesis of linear and branched oligodialkylalkylhydrosiloxanes

Synthesis of linear and branched oligodialkylalkylhydrosiloxanes New linear and branched oligodialkylalkylhydrosiloxanes were prepared by hydrolytic cocondensation of various functional organosilanes with diethyl(dimethyl-)dichlorosilane, ethylhydro-(methylhydro-) dichlorosilane, and trimethylchlorosilane, followed by catalytic rearrangement in the presence of an electrophilic catalyst. The products are of interest as hydrophobizing agents and starting compounds for replacement of hydrogen atoms at silicon by other substituents. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Synthesis of linear and branched oligodialkylalkylhydrosiloxanes

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Publisher
Springer Journals
Copyright
Copyright © 2011 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S107042721103027X
Publisher site
See Article on Publisher Site

Abstract

New linear and branched oligodialkylalkylhydrosiloxanes were prepared by hydrolytic cocondensation of various functional organosilanes with diethyl(dimethyl-)dichlorosilane, ethylhydro-(methylhydro-) dichlorosilane, and trimethylchlorosilane, followed by catalytic rearrangement in the presence of an electrophilic catalyst. The products are of interest as hydrophobizing agents and starting compounds for replacement of hydrogen atoms at silicon by other substituents.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Apr 19, 2011

References

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