Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes

Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes α-Hydroxyalkyl peroxide esters and ethers containing, along with the peroxy bond, also acyloxy and alkoxy groups, are effective initiators of radical processes. The initiation efficiency is due to the capability of these molecules to generate simultaneously oxygen- and carbon-centered radicals capable of hydrogen abstraction from the substrate and of addition to ⟩C=C⟨ bonds. The selectivity of the synthesis of α-hydroxyalkyl peroxide esters and ethers is mainly determined by the steps of the synthesis and isolation of the intermediate α-chloroalkyl peroxides, because of their high reactivity. Experimental conditions allowing control of the synthesis of α-hydroxyalkyl peroxide esters and ethers were found. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes

Loading next page...
 
/lp/springer_journal/synthesis-of-hydroxyalkyl-peroxide-esters-and-ethers-as-initiators-of-Y236PEIPXg
Publisher
Springer Journals
Copyright
Copyright © 2014 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427214120167
Publisher site
See Article on Publisher Site

Abstract

α-Hydroxyalkyl peroxide esters and ethers containing, along with the peroxy bond, also acyloxy and alkoxy groups, are effective initiators of radical processes. The initiation efficiency is due to the capability of these molecules to generate simultaneously oxygen- and carbon-centered radicals capable of hydrogen abstraction from the substrate and of addition to ⟩C=C⟨ bonds. The selectivity of the synthesis of α-hydroxyalkyl peroxide esters and ethers is mainly determined by the steps of the synthesis and isolation of the intermediate α-chloroalkyl peroxides, because of their high reactivity. Experimental conditions allowing control of the synthesis of α-hydroxyalkyl peroxide esters and ethers were found.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Mar 25, 2015

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create lists to
organize your research

Export lists, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off