Synthesis of high surface area NiO nanoparticles through thermal decomposition of mixed ligand Ni(II) Complex, [Ni(binol)(bpy)]∙CH3OH

Synthesis of high surface area NiO nanoparticles through thermal decomposition of mixed ligand... The present work focuses on the synthesis of high surface area NiO nanoparticles through thermal decomposition of [Ni(binol)(bpy)]∙CH3OH complex as a new precursor. [Ni(binol)(bpy)]∙CH3OH (where binol = racemic-1,1′-bi-2-naphtholate and bpy = 2,2′-bipyridine) was synthesized from reaction of NiCl2(bpy) with rac-Na2(binol). The complex was characterized by elemental analysis and spectroscopy techniques of IR, UV-Vis, mass, 1H and 13C NMR. The results revealed that [Ni(binol)(bpy)]∙CH3OH was a paramagnetic tetrahedral complex. The physicochemical properties of the nanoparticles were characterized by various analysis techniques such as X-ray diffraction (XRD), Fourier transform infrared (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and BET specific surface area. The used synthetic rout is facile and economic that makes it suitable for large scale production of pure nickel oxide nanoparticles. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Synthesis of high surface area NiO nanoparticles through thermal decomposition of mixed ligand Ni(II) Complex, [Ni(binol)(bpy)]∙CH3OH

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Publisher
Springer Journals
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S10704272160010109
Publisher site
See Article on Publisher Site

Abstract

The present work focuses on the synthesis of high surface area NiO nanoparticles through thermal decomposition of [Ni(binol)(bpy)]∙CH3OH complex as a new precursor. [Ni(binol)(bpy)]∙CH3OH (where binol = racemic-1,1′-bi-2-naphtholate and bpy = 2,2′-bipyridine) was synthesized from reaction of NiCl2(bpy) with rac-Na2(binol). The complex was characterized by elemental analysis and spectroscopy techniques of IR, UV-Vis, mass, 1H and 13C NMR. The results revealed that [Ni(binol)(bpy)]∙CH3OH was a paramagnetic tetrahedral complex. The physicochemical properties of the nanoparticles were characterized by various analysis techniques such as X-ray diffraction (XRD), Fourier transform infrared (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and BET specific surface area. The used synthetic rout is facile and economic that makes it suitable for large scale production of pure nickel oxide nanoparticles.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: May 19, 2016

References

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