Access the full text.
Sign up today, get DeepDyve free for 14 days.
A. Addison, T. Rao, J. Reedijk, J. Rijn, G. Verschoor (1984)
Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(II) perchlorateJournal of The Chemical Society-dalton Transactions
(1997)
SHELXS-97: Program for Crystal Structure Solution
W. Liaw, Chien‐Ming Lee, Gene-Hsiang Lee, S. Peng (1998)
SYNTHESIS AND CHARACTERIZATION OF THE FIVE-COORDINATE SIXTEEN-ELECTRON MANGANESE(I) COMPLEX MN(CO)3(S-C6H4-NH)-Inorganic Chemistry, 37
W. Liaw, Chih-Yuan Chuang, Way-Zen Lee, Chen-Kang Lee, Gene-Hsiang Lee, S. Peng (1996)
An Approach to Heterometallic Complexes with Selenolate and Tellurolate Ligands: Crystal Structures of cis-[Mn(CO)(4)(SePh)(2)](-), [(CO)(3)Mn(&mgr;-SeMe)(3)Mn(CO)(3)](-), (CO)(4)Mn(&mgr;-TePh)(2)Co(CO)(&mgr;-SePh)(3)Mn(CO)(3), and (CO)(3)Mn(&mgr;-SePh)(3)Fe(CO)(3).Inorganic chemistry, 35 9
Chien‐Ming Lee, G. Lin, C. Hsieh, Ching‐Han Hu, Gene-Hsiang Lee, S. Peng, W. Liaw (1999)
A five-coordinate, sixteen-electron manganese(I) complex [Mn(CO)3(S,S–C6H4)]– stabilized by S,S π-donation from chelating [S,S–C6H4]2–Journal of The Chemical Society-dalton Transactions
(2001)
SADABS: Program for Absorption Correction of Area Detector Frames (Bruker
N. Begum, Md. Hyder, S. Kabir, G. Hossain, E. Nordlander, Dalia Rokhsana, E. Rosenberg (2005)
Dithiolate complexes of manganese and rhenium: X-ray structure and properties of an unusual mixed valence cluster Mn3(CO)6(mu-eta2-SCH2CH2CH2S)3.Inorganic chemistry, 44 26
(1997)
SHELXL-97: Program for Crystal Structure Refinement
W. Liaw, S. Chiou, Gene-Hsiang Lee, S. Peng (1998)
A Discrete Chlorotellurate [Cl4Te-Mn(CO)5]-: Coordinative Addition of the Metalloanion [Mn(CO)5]- to TeCl4Inorganic Chemistry, 37
W. Liaw, C. Hsieh, G. Lin, Gene-Hsiang Lee (2001)
Syntheses, Reactivity, and π-Donating Ligand Metathesis Reaction of Five-Coordinate Sixteen-Electron Manganese(I) Complexes: Crystal Structures of [Mn(CO)3(−TeC6H4-o-NH−)]-, [(Mn(CO)3)2(μ-SC6H4-o-S−S−C6H4-o-μ-S−)], [(CO)3Mn(μ-SC6H4-o-NH2−)]2, and [(CO)3Mn(μ-SC8N2H4-o-S−)]22-Inorganic Chemistry, 40
W. Liaw, Chao-Yi Ching, Chen-Kang Lee, Gene-Hsiang Lee, S. Peng (1996)
Oxidative Addition of Diphenyl Disulfide/Thiophenol to [Mn(CO)5]−: Crystal Structure of cis‐[Mn(CO)4(SPh)2]−Journal of The Chinese Chemical Society, 43
S. Mandal, L. Thompson, M. Newlands, E. Gabe (1989)
Structural, magnetic, and electrochemical studies on macrocyclic dicopper(II) complexes with varying chelate ring sizeInorganic Chemistry, 28
C. Macrae, P. Edgington, Patrick McCabe, E. Pidcock, G. Shields, Robin Taylor, Matthew Towler, J. Streek (2006)
Mercury: visualization and analysis of crystal structuresJournal of Applied Crystallography, 39
W. Liaw, C. Hsieh, S. Peng, Gene-Hsiang Lee (2002)
SS Bond-activation of diorganyl disulfide by anionic [Mn(CO)5]−: crystal structures of [MnII(SC5H4NO)3]− and [(CO)3Mn(μ-SR)3Co(μ-SR)3Mn(CO)3]− (R=C6H4NHCOPh)Inorganica Chimica Acta, 332
K. Inkrott, R. Goetze, S. Shore (1978)
Preparation of metal carbonylate anions by hydride reductionJournal of Organometallic Chemistry, 154
C. Hsieh, Shengda Ding, Ö. Erdem, Danielle Crouthers, T. Liu, Charles McCrory, W. Lubitz, C. Popescu, J. Reibenspies, M. Hall, M. Darensbourg (2014)
Redox active iron nitrosyl units in proton reduction electrocatalysisNature Communications, 5
Oxidative addition of Br2 to [Mn(CO)5]− leads to the formation of [(CO)4MnBr], followed by the ligand exchange of bromide to [S,Se-C6H3-4-Me] 2 2− to form complex (CO)3Mn (µ-ŋ 4-SC6H3-4-(CH3)Se-SeC6H3-4-(CH3)S)Mn(CO)3 (1). A new five-coordinate complex [(CO)3Mn(-S,-Se-C6H3-4-CH3)]− (2) can be synthesized through two different routes: (a) oxidative addition of diselenide [HS,Se-C6H3-4-Me]2 to the [Mn(CO)5]− followed by deprotonation and ligand dissociation to generate complex 2; (b) reduction of diselenide bonds of complex 1 by [BH4]− to produce 2. Drop-wise addition of HBF4·OEt2 at 0 °C results in the formation of complex 1. The X-ray analysis shows that complex 2 has relative short Mn–Se and Mn–S bond distances compare to the published structures of cis-[(CO)4Mn(EPh)2]− (E = S and Se; Liaw et al. in J. Chin. Chem. Soc. 43:427–431, 1996; Liaw et al. in Inorg. Chem. 35:2530, 1996). Interestingly, exposure of the coordinated unsaturated complex 2 under CO(g) atmosphere resulted in complex cis-[(CO)4Mn(-S,-Se-C6H3-4-Me)]− (3) being formed. After purging the solution of complex 3 with N2, it was reconverted completely back to complex 2; this observation was characterized by FTIR. The cyclic voltammetry scan of complex 2 shows a quasi-reversible redox couple with E 1/2 = −1.94 V and I pa/I pc = 0.68. Ligand [HS, Se-C6H3-4-CH3]2 and complexes 1 and 2 are all characterized by IR, UV–Vis, NMR, EA and X-ray single crystal diffraction.
Research on Chemical Intermediates – Springer Journals
Published: Jan 28, 2016
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.