The process parameters (temperature, atmosphere, and composition) of the synthesis of complex carbonitrides W1−x Zr x C1−y N y were determined. The area of formation of homogeneous carbonitrides in synthesis from refractory compounds and from WC and zirconium oxide was found. The conditions of appearance of the hemicarbide W2C were elucidated. The possibility of fabricating homogeneous carbonitrides (CNs) at the lower temperature of the synthesis by increasing fineness of the starting components by vibrogrinding was examined.
Russian Journal of Applied Chemistry – Springer Journals
Published: Dec 30, 2005
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