The crystal structure of a chiral α-phenylethylamine tartaric acid salt, and novel application to the cyanosilylation of prochiral ketones Chiral α-ethylphenylamine tartaric acid salts were synthesized from α-ethylphenylamine by direct reaction with chiral tartaric acid. The crystal structure of S -(−)-α-ethylphenylamine-(2 R ,3 R )-(−)-dihydrobutanedioic acid was determined. When the chiral α-ethylphenylamine tartaric acid salts were used as catalysts in the cyanosilylation of prochiral ketones, moderate conversions were obtained(Figure not available: see fulltext.)
Research on Chemical Intermediates – Springer Journals
Published: Mar 11, 2010
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