Synthesis of abietinol and dehydroabietinol polyfluoropolyoxaalkylacylates

Synthesis of abietinol and dehydroabietinol polyfluoropolyoxaalkylacylates New polyfluorinated acylates of diterpene alcohols were prepared by reactions of sodium abietinolate and dihydroabietinolate with perfluoro(2-methyl-3-oxahexanoyl), perfluoro(2,5-dimethyl-3,6-dioxanonanoyl), and perfluoro(2,5,8-trimethyl-3,6,9-trioxaundecanoyl) fluorides, and also of abietinol and dehydroabietinol with heptadecafluorononanoic acid in the presence of catalytic amounts of concentrated sulfuric acid. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Synthesis of abietinol and dehydroabietinol polyfluoropolyoxaalkylacylates

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2013 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427213030142
Publisher site
See Article on Publisher Site

Abstract

New polyfluorinated acylates of diterpene alcohols were prepared by reactions of sodium abietinolate and dihydroabietinolate with perfluoro(2-methyl-3-oxahexanoyl), perfluoro(2,5-dimethyl-3,6-dioxanonanoyl), and perfluoro(2,5,8-trimethyl-3,6,9-trioxaundecanoyl) fluorides, and also of abietinol and dehydroabietinol with heptadecafluorononanoic acid in the presence of catalytic amounts of concentrated sulfuric acid.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Apr 17, 2013

References

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