Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications

Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications Metal–organic frameworks (MOFs) hybrid composites have recently attracted considerable attention in hydrogen storage applications. In this study a hybrid composite of zeolite templated carbon (ZTC) and Cr-based MOF (MIL-101) was synthesised by adding the templated carbon in situ during the synthesis of MIL-101(Cr). The obtained sample was fully characterized and hydrogen adsorption measurements performed at 77 K up to 1 bar. The results showed that the surface areas and the hydrogen uptake capacities of individual MIL-101 (2552 m2 g−1, 1.91 wt%) and zeolite templated carbon (2577 m2 g−1, 2.39 wt%) could be enhanced when a hybrid MIL-101(Cr)/ZTC composite (2957 m2 g−1, 2.55 wt%) was synthesized. The procedure presents a simple way for enhancement of hydrogen uptake capacity of the individual Cr-MOF and templated carbon samples. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications

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Publisher
Springer Journals
Copyright
Copyright © 2015 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-015-2361-2
Publisher site
See Article on Publisher Site

Abstract

Metal–organic frameworks (MOFs) hybrid composites have recently attracted considerable attention in hydrogen storage applications. In this study a hybrid composite of zeolite templated carbon (ZTC) and Cr-based MOF (MIL-101) was synthesised by adding the templated carbon in situ during the synthesis of MIL-101(Cr). The obtained sample was fully characterized and hydrogen adsorption measurements performed at 77 K up to 1 bar. The results showed that the surface areas and the hydrogen uptake capacities of individual MIL-101 (2552 m2 g−1, 1.91 wt%) and zeolite templated carbon (2577 m2 g−1, 2.39 wt%) could be enhanced when a hybrid MIL-101(Cr)/ZTC composite (2957 m2 g−1, 2.55 wt%) was synthesized. The procedure presents a simple way for enhancement of hydrogen uptake capacity of the individual Cr-MOF and templated carbon samples.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Nov 17, 2015

References

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