Synthesis of 1-(4-isopropenylphenoxy)-bromo-C2-C4-alkanes and application of their transformation products

Synthesis of 1-(4-isopropenylphenoxy)-bromo-C2-C4-alkanes and application of their transformation... Reaction of 4-isopropenylphenol with α,ω-dibromo-C2-C4-alkanes by the Willamson reaction in the presence of potassium iodide as promoter, aiming to synthesize the corresponding monobromosubstituted derivatives and to study their some chemical transformation. Optimal conditions to obtain 1-(4-isopropenylphenoxy)-2-bromoethane, 1-(4-isopropenylphenoxy)-3-bromopropane and 1-(4-isopropenylphenoxy)-4-bromobutane were found. The nitrogen-containing derivatives, inhibitors of a hydrosulfuric corrosion in the water-salt solutions, were obtained on the basis of the first two compounds. The derivatives involving multiple bond and ester-group were synthesized from the third compound. Their incorporation into the polystyrene chains in the process synthesis gives them plasticize properties. Russian Journal of Applied Chemistry Springer Journals

Synthesis of 1-(4-isopropenylphenoxy)-bromo-C2-C4-alkanes and application of their transformation products

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SP MAIK Nauka/Interperiodica
Copyright © 2009 by Pleiades Publishing, Ltd.
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
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