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Synthesis of 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hepta-2,5-dienylmethyl esters of p-substituted benzoic acids

Synthesis of 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hepta-2,5-dienylmethyl esters of... The possibility of preparing 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hepta-2,5-dienyl-methyl esters of p-substituted benzoic acids by [4+2]cycloaddition of tetrachlorodimethoxycyclo-pentadine to propargyl esters of the corresponding acids was examined. The optimal synthesis conditions were found. The structure of the compounds synthesized was confirmed by independent synthesis and by IR and 1H NMR spectroscopy. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Synthesis of 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hepta-2,5-dienylmethyl esters of p-substituted benzoic acids

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References (2)

Publisher
Springer Journals
Copyright
Copyright © 2010 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
DOI
10.1134/S107042721004021X
Publisher site
See Article on Publisher Site

Abstract

The possibility of preparing 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hepta-2,5-dienyl-methyl esters of p-substituted benzoic acids by [4+2]cycloaddition of tetrachlorodimethoxycyclo-pentadine to propargyl esters of the corresponding acids was examined. The optimal synthesis conditions were found. The structure of the compounds synthesized was confirmed by independent synthesis and by IR and 1H NMR spectroscopy.

Journal

Russian Journal of Applied Chemistry – Springer Journals

Published: Jun 4, 2010

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