Synthesis, crystal structures, biological screening and electrochemical analysis of some salen-based transition metal complexes

Synthesis, crystal structures, biological screening and electrochemical analysis of some... A new series of transition metal complexes with (1) Mn(III), (2) Co(II), (3) Ni(II) and (4) Cu(II) have been synthesized by the reaction of [6,6′-((1E,1′E)-(propane-1,3-diylbis(azanylylidene))bis(methanylylidene))bis(5-isopropyl-2-methylphenol)] with suitable metal salts. The synthesized complexes have been characterized by elemental analysis and spectroscopic techniques. The results of single crystal structures show that the metal is bonded to the ligand through the phenolic oxygens and imino nitrogens. Synthesized complexes have been evaluated for antibacterial activity and antioxidant activity, which shows considerable results. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Synthesis, crystal structures, biological screening and electrochemical analysis of some salen-based transition metal complexes

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Publisher
Springer Journals
Copyright
Copyright © 2017 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-017-2917-4
Publisher site
See Article on Publisher Site

Abstract

A new series of transition metal complexes with (1) Mn(III), (2) Co(II), (3) Ni(II) and (4) Cu(II) have been synthesized by the reaction of [6,6′-((1E,1′E)-(propane-1,3-diylbis(azanylylidene))bis(methanylylidene))bis(5-isopropyl-2-methylphenol)] with suitable metal salts. The synthesized complexes have been characterized by elemental analysis and spectroscopic techniques. The results of single crystal structures show that the metal is bonded to the ligand through the phenolic oxygens and imino nitrogens. Synthesized complexes have been evaluated for antibacterial activity and antioxidant activity, which shows considerable results.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Mar 8, 2017

References

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