Synthesis, crystal structures, and photocatalytic properties of two 2D supramolecular silver(I) coordination polymers derived from bis(1,2,4-triazole) and aromatic dicarboxylate ligands

Synthesis, crystal structures, and photocatalytic properties of two 2D supramolecular silver(I)... Two silver(I)-mixed ligand coordination polymers (CPs), {[Ag(L)(Hmip)]·H2O} n (1) and {[Ag(L)]·0.5(DCTP)·H2O]} n (2) (H2mip = 5-methylisophthalic acid, H2DCTP = 2,5-dichloroterephthalic acid, and L = 4,4′-bis(1,2,4-triazol-1-ylmethyl)biphenyl) have been hydrothermally synthesized and structurally characterized. Two CPs display 1D zigzag chain and linear chain structures, respectively. Furthermore, these 1D chains are extended into 2D supramolecular networks through hydrogen bonding interactions. The luminescence properties and photocatalytic behaviors of both CPs are reported. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Transition Metal Chemistry Springer Journals

Synthesis, crystal structures, and photocatalytic properties of two 2D supramolecular silver(I) coordination polymers derived from bis(1,2,4-triazole) and aromatic dicarboxylate ligands

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Publisher
Springer International Publishing
Copyright
Copyright © 2017 by Springer International Publishing AG Switzerland
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry; Organometallic Chemistry
ISSN
0340-4285
eISSN
1572-901X
D.O.I.
10.1007/s11243-017-0155-7
Publisher site
See Article on Publisher Site

Abstract

Two silver(I)-mixed ligand coordination polymers (CPs), {[Ag(L)(Hmip)]·H2O} n (1) and {[Ag(L)]·0.5(DCTP)·H2O]} n (2) (H2mip = 5-methylisophthalic acid, H2DCTP = 2,5-dichloroterephthalic acid, and L = 4,4′-bis(1,2,4-triazol-1-ylmethyl)biphenyl) have been hydrothermally synthesized and structurally characterized. Two CPs display 1D zigzag chain and linear chain structures, respectively. Furthermore, these 1D chains are extended into 2D supramolecular networks through hydrogen bonding interactions. The luminescence properties and photocatalytic behaviors of both CPs are reported.

Journal

Transition Metal ChemistrySpringer Journals

Published: Jun 8, 2017

References

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