A new mononuclear oxovanadium(V) complex, [VOL(OMe)(MeOH)] (I), where L is the dianionic form of (1H-indol-3-yl)acetic acid [1-(2-hydroxynaphthalen-1-yl)methylidene]hydrazine, has been synthesized and characterized by physico-chemical methods and single crystal X-ray determination, (CIF file CCDC no. 858861). The complex crystallizes in the triclinic space group $$P\bar 1$$ with unit cell dimensions a = 10.117(1), b = 10.609(2), c = 11.454(2) Å, α = 99.228(2)°, β = 112.250(2)°, γ = 100.561(2)°, V = 1082.3(3)Å3, Z = 2, R 1 = 0.0512, and wR 2 = 0.1045. The V atom in complex I is in an octahedral coordination. Thermal analysis and preliminary antibacterial activity of complex I were studied.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Jun 24, 2015
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