Synthesis, crystal structure, and porosity of 1D coordination polymer of neodymium(III) with isonicotinic acid and dimeric complex of neodymium(III) with nicotinic acid

Synthesis, crystal structure, and porosity of 1D coordination polymer of neodymium(III) with... A 1D coordination polymer [Nd3(INA)9(H2O)6] n (I) and a dimeric complex with mononuclear asymmetric unit [Nd(NA)3(H2O)2] (II) (HINA = isonicotinic acid and HNA = nicotinic acid) were synthesized. The compounds were characterized by elemental analyses, infrared spectroscopy and single crystal X-ray diffraction studies (CIF file CCDC nos. 938976 (I) and 939061 (II). X-ray crystal structure analysis reveals that both compounds exhibit rich structural chemistry. Compounds I and II belong to the monoclinic system with space group P21/c. Thermogravimetric analysis has been performed to investigate their thermal stability. The coordination polymer I has meso-porous structure with average diameter of pores (∼4 nm) and BET surface area 13.62 m2/g. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis, crystal structure, and porosity of 1D coordination polymer of neodymium(III) with isonicotinic acid and dimeric complex of neodymium(III) with nicotinic acid

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415060068
Publisher site
See Article on Publisher Site

Abstract

A 1D coordination polymer [Nd3(INA)9(H2O)6] n (I) and a dimeric complex with mononuclear asymmetric unit [Nd(NA)3(H2O)2] (II) (HINA = isonicotinic acid and HNA = nicotinic acid) were synthesized. The compounds were characterized by elemental analyses, infrared spectroscopy and single crystal X-ray diffraction studies (CIF file CCDC nos. 938976 (I) and 939061 (II). X-ray crystal structure analysis reveals that both compounds exhibit rich structural chemistry. Compounds I and II belong to the monoclinic system with space group P21/c. Thermogravimetric analysis has been performed to investigate their thermal stability. The coordination polymer I has meso-porous structure with average diameter of pores (∼4 nm) and BET surface area 13.62 m2/g.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Jun 24, 2015

References

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