Synthesis, crystal structure, and magnetic properties of binuclear cobalt(II) complex with 2-(5-{6-[5-(pyrazin-2-yl)-1H-1,2,4-triazol-3-yl]-pyridin-2-yl}-1H-1,2,4-triazol-3-yl)pyrazine

Synthesis, crystal structure, and magnetic properties of binuclear cobalt(II) complex with... The synthesis and crystal structure of a new Co(II) compound with 2-(5-{6-[5-(pyrazin-2-yl)-1H-1,2,4-triazol-3-yl]-pyridin-2-yl}-1H-1,2,4-triazol-3-yl)pyrazine (H2Ptptp) are reported. The new compound [Co2(Ptptp)Cl2(H2O)2] · H2O (I) has been determined by single-crystal X-ray diffraction (CIF file CCDC no. 1010785) and characterized by elemental analyses and infrared spectrum. The structure I consists of two independent Co2+ ions, one Ptptp2− anion, two Cl− anions, two coordinated H2O molecules and one lattice H2O molecule. The three-dimensional (3D) supramolecular architecture is formed through the hydrogen bonds among adjacent units. Moreover, magnetic susceptibility measurements indicate that the compound exhibits weak antiferromagnetic coupling interaction. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis, crystal structure, and magnetic properties of binuclear cobalt(II) complex with 2-(5-{6-[5-(pyrazin-2-yl)-1H-1,2,4-triazol-3-yl]-pyridin-2-yl}-1H-1,2,4-triazol-3-yl)pyrazine

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415030033
Publisher site
See Article on Publisher Site

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