The reaction of AgReO4 with N-(2-aminoethyl)piperazine, C6H15N3 (L), gave a new compound Ag(L)(ReO4)(I). The crystals of I are monoclinic, space group P21/c, a = 15.067(1) Å, b = 11.616(1) Å, c = 14.259(1) Å, β= 108.40(1)°, V = 2368.0(3) Å3, ρ(calcd.) = 2.734 g/cm3, Z = 8. The structure of I consists of cationic polymeric chains [Ag(L)] ∞ + connected to the [ReO4]− anions by the N-H⋯O hydrogen bonds to form a 3D supramolecular assembly. The Ag+ ions have a T-shaped coordination with the ligand N atom functioning as a tridentate bridge between the silver atoms (CIF file CCDC no. 1034044). Compound I possesses fluorescence.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Jun 3, 2015
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