Synthesis, crystal structure, and luminescence of two mono-nuclear zinc(II) complex: ZnII(C10H8N3Br)(SCN)2 and ZnII(C5H6N2)2(SCN)2

Synthesis, crystal structure, and luminescence of two mono-nuclear zinc(II) complex:... Two mononuclear zinc(II) complexes, ZnII(C10H8N3Br)(SCN)2 (I) (C10H8N3Br is 6-bromo-N(pyridin-2-yl)pyridin-2-amine); ZnII(C5H6N2)2(SCN)2 (II) (C5H6N2 is pyridin-2-amine), were synthesized by solvothermal reaction at 393 K. Both structures have been determined on the basis of X-ray diffraction data (CIF files CCDC nos. 1042001 (I) and 1042002 (II)). Complex I crystallized in monoclinic, space group P21/c, with a = 7.4083(10), b = 14.958(2), c = 15.096(2) Å, β = 103.861(2)°, Z = 4, ρcalcd = 1.761 mg/m3, V = 1624.1(4) Å3. Complex II crystallized in monoclinic, space group P21/c, with a = 15.870(6), b = 13.571(5), c = 7.822(3) Å, β = 104.200(4)°, Z = 4, ρcalcd = 1.504 mg/m3, V = 1633.2(11) Å3. Complex I shows strong emissions exposing to ultraviolet radiation. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis, crystal structure, and luminescence of two mono-nuclear zinc(II) complex: ZnII(C10H8N3Br)(SCN)2 and ZnII(C5H6N2)2(SCN)2

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415090080
Publisher site
See Article on Publisher Site

Abstract

Two mononuclear zinc(II) complexes, ZnII(C10H8N3Br)(SCN)2 (I) (C10H8N3Br is 6-bromo-N(pyridin-2-yl)pyridin-2-amine); ZnII(C5H6N2)2(SCN)2 (II) (C5H6N2 is pyridin-2-amine), were synthesized by solvothermal reaction at 393 K. Both structures have been determined on the basis of X-ray diffraction data (CIF files CCDC nos. 1042001 (I) and 1042002 (II)). Complex I crystallized in monoclinic, space group P21/c, with a = 7.4083(10), b = 14.958(2), c = 15.096(2) Å, β = 103.861(2)°, Z = 4, ρcalcd = 1.761 mg/m3, V = 1624.1(4) Å3. Complex II crystallized in monoclinic, space group P21/c, with a = 15.870(6), b = 13.571(5), c = 7.822(3) Å, β = 104.200(4)°, Z = 4, ρcalcd = 1.504 mg/m3, V = 1633.2(11) Å3. Complex I shows strong emissions exposing to ultraviolet radiation.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Sep 2, 2015

References

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