Colorless crystals of CuL, where L = 3-ethoxysalicylaldehyde-N,N-bis(3-aminopropyl)methylamine, were obtained by self-assembly of 3-ethoxysalicylaldehyde-N,N-bis(3-aminopropyl)methylamine and Cu(NO3)2·4H2O in 2:1 (v/v) CH3OH–H2O. The Cu(II) complex was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction analysis. The monoclinic crystal belongs to space group P21/c with a = 10.3028(14) Å, b = 14.0255(12) Å, c = 17.355(14) Å, β = 97.474(3)°, V = 2,487(2) Å3, Z = 4, D c = 1.344 g cm−3, μ = 0.913 mm−1, F(000) = 1,060, and final R = 0.0563, ωR = 0.0995. In the crystal structure, each Cu(II) atom is five-coordinated in a distorted square pyramid environment by two phenolic O atoms and three N atoms from the ligand. The molecules form a one-dimensional chain structure by intermolecular hydrogen bond interaction. The electrochemical properties of the Cu(II) complex were investigated.
Research on Chemical Intermediates – Springer Journals
Published: Jun 6, 2013
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera